Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004272885> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2004272885 endingPage "273" @default.
- W2004272885 startingPage "269" @default.
- W2004272885 abstract "Water and acetic acid eliminations from 1-tetralin radical cations have been shown previously to be highly regiospecific 1,4 processes. Utilizing deuterium labeling, high resolution peak ratio measurements and metastable ion defocusing techniques, the stereochemistry of these processes has been investigated. cis-4-d1- and trans-4-d1-1-Tetralol both lose HOH and DOH in appreciable amounts; similarly, both acetoxy derivatives lose HOAc and DOAc. These results are interpreted in terms of an ionic epimerization which operates in competition with a stereospecific 1,4 elimination mechanism. A hydrogen exchange process which occurs between the 4-carbon and the oxygen atom situated on the 1-carbon of 1-tetralol has also been observed. This process accounts for observed H/D ratios in the ethene elimination reaction of various deuterium labeled 1-tetralols." @default.
- W2004272885 created "2016-06-24" @default.
- W2004272885 creator A5013111399 @default.
- W2004272885 creator A5031479644 @default.
- W2004272885 date "1982-06-01" @default.
- W2004272885 modified "2023-10-14" @default.
- W2004272885 title "Stereochemistry of HOH and HOAc elimination from 1-tetralol and 1-acetoxytetralin radical cations" @default.
- W2004272885 cites W1480052477 @default.
- W2004272885 cites W1984272631 @default.
- W2004272885 cites W1986621785 @default.
- W2004272885 cites W2021445658 @default.
- W2004272885 cites W2027089577 @default.
- W2004272885 cites W2049605206 @default.
- W2004272885 cites W2076527577 @default.
- W2004272885 cites W2081446747 @default.
- W2004272885 cites W2093051228 @default.
- W2004272885 cites W2330989917 @default.
- W2004272885 cites W3004836569 @default.
- W2004272885 cites W4245702125 @default.
- W2004272885 doi "https://doi.org/10.1002/oms.1210170606" @default.
- W2004272885 hasPublicationYear "1982" @default.
- W2004272885 type Work @default.
- W2004272885 sameAs 2004272885 @default.
- W2004272885 citedByCount "8" @default.
- W2004272885 crossrefType "journal-article" @default.
- W2004272885 hasAuthorship W2004272885A5013111399 @default.
- W2004272885 hasAuthorship W2004272885A5031479644 @default.
- W2004272885 hasConcept C121332964 @default.
- W2004272885 hasConcept C155647269 @default.
- W2004272885 hasConcept C161790260 @default.
- W2004272885 hasConcept C167569220 @default.
- W2004272885 hasConcept C178790620 @default.
- W2004272885 hasConcept C185592680 @default.
- W2004272885 hasConcept C187921627 @default.
- W2004272885 hasConcept C203130289 @default.
- W2004272885 hasConcept C2776673659 @default.
- W2004272885 hasConcept C2779293432 @default.
- W2004272885 hasConcept C512968161 @default.
- W2004272885 hasConcept C58364064 @default.
- W2004272885 hasConcept C62520636 @default.
- W2004272885 hasConcept C71240020 @default.
- W2004272885 hasConcept C94412978 @default.
- W2004272885 hasConceptScore W2004272885C121332964 @default.
- W2004272885 hasConceptScore W2004272885C155647269 @default.
- W2004272885 hasConceptScore W2004272885C161790260 @default.
- W2004272885 hasConceptScore W2004272885C167569220 @default.
- W2004272885 hasConceptScore W2004272885C178790620 @default.
- W2004272885 hasConceptScore W2004272885C185592680 @default.
- W2004272885 hasConceptScore W2004272885C187921627 @default.
- W2004272885 hasConceptScore W2004272885C203130289 @default.
- W2004272885 hasConceptScore W2004272885C2776673659 @default.
- W2004272885 hasConceptScore W2004272885C2779293432 @default.
- W2004272885 hasConceptScore W2004272885C512968161 @default.
- W2004272885 hasConceptScore W2004272885C58364064 @default.
- W2004272885 hasConceptScore W2004272885C62520636 @default.
- W2004272885 hasConceptScore W2004272885C71240020 @default.
- W2004272885 hasConceptScore W2004272885C94412978 @default.
- W2004272885 hasIssue "6" @default.
- W2004272885 hasLocation W20042728851 @default.
- W2004272885 hasOpenAccess W2004272885 @default.
- W2004272885 hasPrimaryLocation W20042728851 @default.
- W2004272885 hasRelatedWork W1987179084 @default.
- W2004272885 hasRelatedWork W1993478875 @default.
- W2004272885 hasRelatedWork W2004272885 @default.
- W2004272885 hasRelatedWork W2041049249 @default.
- W2004272885 hasRelatedWork W2056224812 @default.
- W2004272885 hasRelatedWork W2063482854 @default.
- W2004272885 hasRelatedWork W2091397225 @default.
- W2004272885 hasRelatedWork W2097159897 @default.
- W2004272885 hasRelatedWork W2141211741 @default.
- W2004272885 hasRelatedWork W2402944583 @default.
- W2004272885 hasVolume "17" @default.
- W2004272885 isParatext "false" @default.
- W2004272885 isRetracted "false" @default.
- W2004272885 magId "2004272885" @default.
- W2004272885 workType "article" @default.