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- W2004274760 abstract "The 1:1 molecular complexes between SO/sub 3/ and a series of oxygen-containing bases have been isolated and characterized in nitrogen matrices. The spectra of the complexes all showed a red shift and splitting of the antisymmetric stretching mode of the SO/sub 3/ subunit in the complex, typified by product bands at 1362 and 1378 cm/sup -1/ in the complex with dimethyl ether. A number of perturbed vibrational modes of the base subunit were observed as well, and generally arose from vibrations involving motion of the oxygen atom of the base. A comparison of the shift of the perturbed base modes in these complexes with previously studied complexes indicated that SO/sub 3/ is a very strong Lewis acid, although only small shifts were observed for the SO/sub 3/ subunit, and the symmetric stretching mode was not activated to a detectable degree." @default.
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- W2004274760 date "1986-09-01" @default.
- W2004274760 modified "2023-09-26" @default.
- W2004274760 title "Matrix isolation infrared spectra of the 1:1 molecular complexes of sulfur trioxide with selected oxygen-containing bases" @default.
- W2004274760 doi "https://doi.org/10.1021/j100410a011" @default.
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