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- W2004275887 abstract "Two selections have been found to occur in the crystal growth induced by a monolayer of 9-(hexadecylimino)-4,5-diazafluorene. Between CuSO4·5H2O and Na2SO4·7H2O, although both were supersaturated, only the former was chosen to nucleate under the monolayer and the latter formed at the bottom of the container. Furthermore, among all of the crystal faces of CuSO4·5H2O, the (010) face was selected by the monolayer and the crystallization was oriented. In these processes, the monolayer plays a very important role and acts as a template which can recognize a certain crystal and a certain crystal face. This is due to specific molecular interactions between ions and the hydrophilic head groups of the monolayer, and the influence of some factors including ion binding, lattice matching and structural complementarity. Using the principles of hard–soft acid–base theory, coordination theory and by computer simulation, it was found that the dimensions of the (010) face of CuSO4·5H2O match those of the monolayer very well." @default.
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- W2004275887 title "Selective crystallization between CuSO<sub>4</sub>·5H<sub>2</sub>O and Na<sub>2</sub>SO<sub>4</sub>·7H<sub>2</sub>O under a monolayer" @default.
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- W2004275887 doi "https://doi.org/10.1039/dt9960004439" @default.
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