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- W2004282885 abstract "Abstract Complexes [ML 3 ] 2+ of the bidentate ligand 2‐(1 H ‐imidazol‐2‐yl)pyridine were prepared with iron(II), cobalt(II), and ruthenium(II). The electronic spectra suggest the ligand to be a weaker σ ‐donor and π ‐acceptor than the closely related 2,2′‐bipyridine. The complexes are readily deprotonated by addition of base, and the effect of the deprotonation is to lower the M III /M II redox potential by roughly 900 mV. This is roughly 75% of the drop observed for related complexes of 2,6‐di‐1 H ‐imidazol‐2‐ylpyridine, and suggests the effect to be largely coulombic in origin." @default.
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- W2004282885 date "2005-03-01" @default.
- W2004282885 modified "2023-10-18" @default.
- W2004282885 title "Control of Redox Potential by Deprotonation of Coordinated 1H-Imidazole in Complexes of 2-(1H-Imidazol-2-yl)pyridine" @default.
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- W2004282885 doi "https://doi.org/10.1002/hlca.200590033" @default.
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