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- W2004289002 abstract "Durch Umsetzung von (Benzol)tricarbonylchrom (1) mit ClNO oder NOPF6 in Lösung (CH2Cl2, THF oder CH3CN) lassen sich solvatisierte Mono- und Dinitrosylchrom-Zwischenstufen erhalten, die zur Synthese von oktaedrischen Nitrosylchrom-Verbindungen dienen können. Als Beispiel wird die Darstellung der tert-Butylisonitril-Komplexe CrCl2(NO)2L2 (8), CrCl(CO)n(NO)L4−n (n = 2, 1 und 0) (9a–c), [CrCl(NO)L4]PF6 (10), [Cr(CO)n(NO)L5−n]PF6 (n = 2, 1 und 0) (11a–c), [Cr(NO)2L4](PF6)2 (12) und Cr(NO)2L2[S2CC(CN)2] (13) beschrieben (L = tert-Butylisonitril). Die Konstitutionen der neuen Komplexe werden anhand ihrer IR- und 1H-NMR-Spektren diskutiert. Studies Related to the Synthesis of Octahedral Nitrosylchromium Complexes from (Benzene)tricarbonylchromium The reaction of (benzene)tricarbonylchromium (1) with either ClNO or NOPF6 in solution (CH2Cl2, THF or CH3CN) leads to solvated mono- and dinitrosylchromium intermediates which may be used for the synthesis of octahedral nitrosylchromium compounds. This is shown by the preparation of the tert-butyl isocyanide (L) complexes CrCl2(NO)2L2 (8), CrCl(CO)n(NO)L4−n (n = 2, 1 and 0) (9a–c), [CrCl(NO)L4]PF6 (10), [Cr(CO)n(NO)L5−n]PF6 (n = 2, 1 and 0) (11a–c), [Cr(NO)2L4](PF6)2 (12), and Cr(NO)2L2[S2CC(CN)2] (13). The structures of the new complexes are discussed on the basis of their IR and 1H NMR spectra." @default.
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- W2004289002 date "1982-04-01" @default.
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- W2004289002 title "Untersuchungen zur Synthese oktaedrischer Nitrosylchrom‐Komplexe aus (Benzol)tricarbonylchrom" @default.
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- W2004289002 doi "https://doi.org/10.1002/cber.19821150418" @default.
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