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- W2004289316 abstract "trans,trans-1-(Aminomethyl)-2-methoxy-3-phenylcyclopropane (3) was synthesized in three steps from (Z)-beta-methoxystyrene and ethyl diazoacetate. Compound 3 was shown to be a substrate and inactivator of mitochondrial beef liver monoamine oxidase (MAO) with a partition ratio of 1428. MAO-catalyzed oxidation of 3 produces one major metabolite, isolated and identified by GCOSY, GHMQC, and GHMBC NMR techniques to be trans,trans-2-methoxy-3-phenyl-1-N-[(3-phenyl-N-pyrrolyl)methyl]cyclopropane (7). A mechanism, supported by a model reaction, is proposed for the formation of this metabolite." @default.
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- W2004289316 date "1996-01-01" @default.
- W2004289316 modified "2023-10-16" @default.
- W2004289316 title "Monoamine Oxidase-Catalyzed Oxidative Rearrangement oftrans,trans-1-(Aminomethyl)-2-methoxy-3-phenylcyclopropane" @default.
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- W2004289316 doi "https://doi.org/10.1021/jo961540a" @default.
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