Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004296275> ?p ?o ?g. }
- W2004296275 endingPage "32" @default.
- W2004296275 startingPage "22" @default.
- W2004296275 abstract "The mechanism of the dehalogenation step catalyzed by dehaloperoxidase (DHP) from Amphitrite ornata, an unusual heme-containing protein with a globin fold and peroxidase activity, has remarkable similarity with that of the classical heme peroxidase, horseradish peroxidase (HRP). Based on quantum mechanical/molecular mechanical (QM/MM) modeling and experimentally determined chlorine kinetic isotope effects, we have concluded that two sequential one electron oxidations of the halogenated phenol substrate leads to a cationic intermediate that strongly resembles a Meisenheimer intermediate - a commonly formed reactive complex during nucleophilic aromatic substitution reactions especially in the case of arenes carrying electron withdrawing groups." @default.
- W2004296275 created "2016-06-24" @default.
- W2004296275 creator A5026514626 @default.
- W2004296275 creator A5054689500 @default.
- W2004296275 creator A5055001948 @default.
- W2004296275 creator A5058041579 @default.
- W2004296275 creator A5073868175 @default.
- W2004296275 date "2011-01-01" @default.
- W2004296275 modified "2023-10-18" @default.
- W2004296275 title "Oxidative dechlorination of halogenated phenols catalyzed by two distinct enzymes: Horseradish peroxidase and dehaloperoxidase" @default.
- W2004296275 cites W135867663 @default.
- W2004296275 cites W1551465144 @default.
- W2004296275 cites W1965868612 @default.
- W2004296275 cites W1966182479 @default.
- W2004296275 cites W1968124667 @default.
- W2004296275 cites W1976499671 @default.
- W2004296275 cites W1980476302 @default.
- W2004296275 cites W1981782561 @default.
- W2004296275 cites W1984386147 @default.
- W2004296275 cites W1986430379 @default.
- W2004296275 cites W1987722678 @default.
- W2004296275 cites W1990030173 @default.
- W2004296275 cites W1994035230 @default.
- W2004296275 cites W2000142522 @default.
- W2004296275 cites W2000783105 @default.
- W2004296275 cites W2006041360 @default.
- W2004296275 cites W2011143647 @default.
- W2004296275 cites W2014697537 @default.
- W2004296275 cites W2021776386 @default.
- W2004296275 cites W2021797822 @default.
- W2004296275 cites W2023271753 @default.
- W2004296275 cites W2023822479 @default.
- W2004296275 cites W2025485802 @default.
- W2004296275 cites W2030795020 @default.
- W2004296275 cites W2033636619 @default.
- W2004296275 cites W2035955622 @default.
- W2004296275 cites W2044409792 @default.
- W2004296275 cites W2051381895 @default.
- W2004296275 cites W2054357498 @default.
- W2004296275 cites W2067077178 @default.
- W2004296275 cites W2073637781 @default.
- W2004296275 cites W2074953269 @default.
- W2004296275 cites W2080215794 @default.
- W2004296275 cites W2084666322 @default.
- W2004296275 cites W2085336624 @default.
- W2004296275 cites W2086073464 @default.
- W2004296275 cites W2087800673 @default.
- W2004296275 cites W2089665039 @default.
- W2004296275 cites W2090392071 @default.
- W2004296275 cites W2095814927 @default.
- W2004296275 cites W2097444598 @default.
- W2004296275 cites W2101537349 @default.
- W2004296275 cites W2109124200 @default.
- W2004296275 cites W2117084999 @default.
- W2004296275 cites W2117999566 @default.
- W2004296275 cites W2123743784 @default.
- W2004296275 cites W2127224181 @default.
- W2004296275 cites W2128430676 @default.
- W2004296275 cites W2131563992 @default.
- W2004296275 cites W2134569508 @default.
- W2004296275 cites W2137056475 @default.
- W2004296275 cites W2138393107 @default.
- W2004296275 cites W2143981217 @default.
- W2004296275 cites W2148003911 @default.
- W2004296275 cites W2150697053 @default.
- W2004296275 cites W2151334055 @default.
- W2004296275 cites W2156562187 @default.
- W2004296275 cites W2164147460 @default.
- W2004296275 cites W2323824312 @default.
- W2004296275 cites W4318716729 @default.
- W2004296275 cites W52301778 @default.
- W2004296275 cites W55504300 @default.
- W2004296275 doi "https://doi.org/10.1016/j.abb.2010.09.018" @default.
- W2004296275 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20869943" @default.
- W2004296275 hasPublicationYear "2011" @default.
- W2004296275 type Work @default.
- W2004296275 sameAs 2004296275 @default.
- W2004296275 citedByCount "22" @default.
- W2004296275 countsByYear W20042962752012 @default.
- W2004296275 countsByYear W20042962752013 @default.
- W2004296275 countsByYear W20042962752014 @default.
- W2004296275 countsByYear W20042962752015 @default.
- W2004296275 countsByYear W20042962752016 @default.
- W2004296275 countsByYear W20042962752017 @default.
- W2004296275 countsByYear W20042962752018 @default.
- W2004296275 countsByYear W20042962752020 @default.
- W2004296275 countsByYear W20042962752021 @default.
- W2004296275 countsByYear W20042962752022 @default.
- W2004296275 countsByYear W20042962752023 @default.
- W2004296275 crossrefType "journal-article" @default.
- W2004296275 hasAuthorship W2004296275A5026514626 @default.
- W2004296275 hasAuthorship W2004296275A5054689500 @default.
- W2004296275 hasAuthorship W2004296275A5055001948 @default.
- W2004296275 hasAuthorship W2004296275A5058041579 @default.
- W2004296275 hasAuthorship W2004296275A5073868175 @default.
- W2004296275 hasConcept C111368507 @default.
- W2004296275 hasConcept C127313418 @default.
- W2004296275 hasConcept C161790260 @default.