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- W2004321707 abstract "The dipole moments and NMR spectra of trans-1,2-dichloro- (I), trans-1,2-bromochloro- (II), trans-1,2-dibromo- (III) and trans-1,2-dibromo-1-methylcyclopentane (IV) in several solvents are reported. Special attention is given to the separation of the outer peaks in the low-field part of the NMR spectra, due to the protons in the CHX-moiety. This separation is equal to JAX + JBX and is shown to be correlated linearly with the square of the electric moment. It is proposed that the conformational properties of these molecules be described in terms of a solvent-dependent dynamic equilibrium aa ⇌ ee, with the diaxial conformation predominating even in a highly polar solvent. Each of the two conformers may correspond to the half-chair or the envelope model with the halogen atoms in the most puckered part of the ring. A limited pseudolibration about these forms is possible." @default.
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- W2004321707 date "2010-09-02" @default.
- W2004321707 modified "2023-09-23" @default.
- W2004321707 title "Conformation of non-aromatic ring compounds XXX: Dipole moments, NMR spectra and conformations of some trans-1,2-dihalogenocyclopentanes" @default.
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- W2004321707 doi "https://doi.org/10.1002/recl.19660851003" @default.
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