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- W2004332183 abstract "Effects of organic diluents have been studied on the adduct formation of thenoyltrifluoroacetone (TTA;HA) chelate of europium(III) with a strong neutral donor, tri-n-octyl phosphine oxide (TOPO;S). The tris-TTA chelate EuA3 forms two types of synergic adducts EuA3·S and EuA3·2S. Adduct formation constants KS,m (m = 1, 2) determined in thirteen diluents are strongly diluent-dependent, e.g. log KS,2 = 15.08 in pentane to 7.68 in chloroform. The log KS,m values are correlated to the solubility parameter δorg of the organic diluent by the linear equation, log KS,m = 2Bδorg + constant, where B is a negative constant characterized by the composition of the adduct." @default.
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- W2004332183 date "1981-01-01" @default.
- W2004332183 modified "2023-09-27" @default.
- W2004332183 title "Effect of diluent on synergic extraction of europium by thenoyltrifluoroacetone and tri-n-octyl phosphine oxide" @default.
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- W2004332183 doi "https://doi.org/10.1016/0022-1902(81)80169-8" @default.
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