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- W2004334019 abstract "Abstract A new method was developed for preparation of silicalite-1 microspheres with uniform diameter about 2.5 μm using monodispersed micron-sized poly- styrene-co-divinylbenzene (PSD) porous particles as template. In this method, the PSD particles were impregnated first with tetraethoxysilane (TEOS) and then with tetrapropylammonium hydroxide (TPAOH). After crystallization and calcination, the silicalite-1 microspheres, possessing a regularly spherical morphology similar to the original silicalite-1, were successfully synthesized. More importantly, the silicalite-1 microspheres have large secondary pores in the range of 40 to 120 nm and high pore volume up to 0.7 cm3g− 1. All these would facilitate the applications of microspheres in catalysis avoiding diffusion limitation." @default.
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- W2004334019 date "2010-06-01" @default.
- W2004334019 modified "2023-10-18" @default.
- W2004334019 title "Preparation of uniform Silicalite-1 microspheres with large secondary pore architecture using monodisperse porous polystyrene particles as template" @default.
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- W2004334019 doi "https://doi.org/10.1016/j.matlet.2010.03.027" @default.
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