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- W2004335598 abstract "Abstract The present paper describes the identification of two stable end products of α‐tocopherol oxidation that were previously detected among the products of the reaction of α‐tocopherol with superoxide anion (O 2 − ) under aprotic conditions. One compound, previously designated compound A, was identified as trans ‐7‐hydroxy‐ trans ‐8,8a‐epoxy‐α‐tocopherone, and the other, designated compound B, was identified as cis ‐7‐hydroxy‐ cis ‐8,8a‐epoxy‐α‐tocopherone. It was also observed that under protic conditions (10% water in acetonitrile) the reaction of α‐tocopherol with O 2 − did not produce compounds A and B, but rather α‐tocopheryl quinone, α‐tocopherol dimer, α‐tocopherol dihydroxy dimer, and the previously designated compound C. Compound C was identified in the present study as α‐tocopheryl‐quinone‐2,3‐epoxide." @default.
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- W2004335598 title "α-tocopherol oxidation mediated by superoxide anion (O 2 − ). II. Identification of the stable α-tocopherol oxidation products" @default.
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- W2004335598 doi "https://doi.org/10.1007/bf02536179" @default.
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