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• W2004341709 endingPage "3849" @default.
• W2004341709 startingPage "3838" @default.
• W2004341709 abstract "In this paper, the adsorption energy of an acicular (prolate and cylindrical) particle onto a liquid-fluid interface and the effect of the line tension are investigated. The results show that, without line tension, acicular particles always prefer to lie flat in the plane of the interface. However, line tension plays a significant role in determining the adsorption of an acicular particle. First, the line tension creates an energy barrier for the adsorption of particles onto an interface. The planar configuration has a larger energy barrier due to the longer contact line. Therefore, the particles prefer to enter the interface in a homeotropic configuration and then rearrange to a planar configuration or an oblique configuration with a small tilt angle. Second, for prolate particles, an energy maximum occurs at some tilt angles when the line tension is large. Therefore, once the prolate particle is adsorbed on the interface in a homeotropic configuration or with a larger tilt angle, it must conquer an energy barrier to rearrange to a planar configuration. For cylindrical particles, when the line tension is higher, the planar configuration will not be the most energy-favorable configuration. The cylindrical particles prefer to stay in the interface with a small tilt angle." @default.
• W2004341709 created "2016-06-24" @default.
• W2004341709 creator A5027382090 @default.
• W2004341709 creator A5041988068 @default.
• W2004341709 date "2005-03-18" @default.
• W2004341709 modified "2023-09-27" @default.
• W2004341709 title "Adsorption of Acicular Particles at Liquid−Fluid Interfaces and the Influence of the Line Tension" @default.
• W2004341709 cites W1974132757 @default.
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• W2004341709 doi "https://doi.org/10.1021/la047851v" @default.
• W2004341709 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15835945" @default.
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