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- W2004344557 abstract "Numerical calculations of the energy of the van der Waals interaction between two spheres of polystyrene in water, n-heptane and vacuum are carried out using some recent developments of the Lifshitz theory. The results are compared with the Hamaker theory of the interaction. It is found that the Hamaker theory gives a qualitatively incorrect picture of the dependence of the interaction on separation when the dielectric permittivities of the spheres and the medium are very different. In particular, if the medium be water, the microwave contribution to the interaction energy is not described at all adequately by the Hamaker theory. If the dielectric permittivities are fairly similar, then the Hamaker theory can be made to describe the interaction fairly well, both qualitatively and quantitatively." @default.
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- W2004344557 date "1973-10-01" @default.
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- W2004344557 title "Deviations of the van der waals energy for two interacting spheres from the predictions of Hamaker theory" @default.
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- W2004344557 doi "https://doi.org/10.1016/0021-9797(73)90242-7" @default.
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