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- W2004351504 abstract "Abstract CaO-based CO 2 sorbents derived from various calcium and aluminum precursors were prepared by a wet mixing method and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and N 2 adsorption–desorption techniques. The as-prepared sorbents consisted of active CaO and inert support materials that could be Al 2 O 3 , Ca 12 Al 14 O 33 or Ca 9 Al 6 O 18 , depending on calcium and aluminum precursors used during the preparation process. A formation mechanism for the inert support materials was proposed. Compared to pure CaO, most of the synthetic CaO-based sorbents showed much higher CO 2 capture capability and stability over multiple carbonation/calcination cycles, which was ascribed to the relatively high specific surface area of the sorbents, the bimodal pore-size distribution with a fair number of small pores, and the inert support material that can effectively prevent or delay sintering of CaO particles. Among these synthetic sorbents the CaO–Ca 9 Al 6 O 18 sorbent with a CaO content of 80 wt% (weight fraction) derived from calcium citrate and aluminum nitrate exhibited the best performance for CO 2 capture, and can be expected to be applied in the sorption-enhanced steam methane reforming process." @default.
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- W2004351504 date "2012-05-01" @default.
- W2004351504 modified "2023-09-27" @default.
- W2004351504 title "Synthesis of CaO-based sorbents through incorporation of alumina/aluminate and their CO2 capture performance" @default.
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