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- W2004352295 abstract "The erythro-thioimidazole precursor to the cyclopropyloxiranylmethyl radical has been prepared. Treatment with 7–19 equiv. of triphenyltin hydride at 70°C gave only 3-cyclopropylprop-2-en-1-ol, the product of epoxide ring opening. No product in which the cyclopropyl ring had opened was observed. Kinetic analysis allowed the assignment of a lower limit for the rate of oxiranylcarbinyl radical rearrangements of 1 × 1010 s−1 at this temperature." @default.
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- W2004352295 title "Radical reactions of epoxides. 2. intramolecular competition between cyclopropylmethyl and oxiranylmethyl radical ring-opening rearrangements" @default.
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- W2004352295 doi "https://doi.org/10.1002/poc.610060406" @default.
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