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- W2004354212 abstract "New bio-inspired polymer composites of alginic acid (AA) and heterocyclic molecules: benzimidazole (BnIm) and pyrazole (Py) were created and characterized by FT-NIR Raman and impedance spectroscopy. The obtained films with various molar ratios of AA and heterocyclic molecules are homogeneous, with good mechanical properties. Raman spectra recorded at room temperature revealed that the obtained films are of a new compound with a different molecular structure and physical properties compared with pure substrates: AA and BnIm and Py. Raman band related to vibration of COOH entity at 1740 cm−1 of AA disappears in the AA : BnIm composites, in which new Raman band related to COO− was found. Additionally, characteristic lines observed in polymer composites which may be associated with vibrations of NH groups can be attributed to the linking of proton to deprotonated N atom in BnIm group. Possibility of such proton exchange is a promising property, which might facilitate the application of obtained composites to anhydrous proton conducting electrolytes in fuel cells." @default.
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- W2004354212 date "2010-10-01" @default.
- W2004354212 modified "2023-09-25" @default.
- W2004354212 title "FT-NIR Raman and proton conductivity studies of new polymer composite: alginic acid–heterocyclic molecules" @default.
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- W2004354212 doi "https://doi.org/10.1080/01411594.2010.509154" @default.
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