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- W2004355321 abstract "Catalytic reduction of NO2 in the presence of excess oxygen and NO has been studied over a 0.2% Pd/SiO2 catalyst between 120 and 260 °C. CO is effective in selective reduction of NO2 at temperatures below 180 °C. Temperature programmed desorption (TPD) and FT-IR studies have been used to investigate the adsorption sites during the reaction conditions. A Langmuir–Hinshelwood mechanism involving oxidised Pd sites is proposed for the reduction of NO2 with CO, where both reactants adsorb competitively on Pd2+ sites. Cl deactivates the catalyst for the reduction of NO2 with CO. This problem can be overcome by using propylene as a co-reductant. Furthermore, addition of propylene widens the temperature window of operation." @default.
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- W2004355321 date "2004-07-01" @default.
- W2004355321 modified "2023-09-27" @default.
- W2004355321 title "Selective removal of NO2 in the presence of oxygen and NO over Pd/SiO2 catalysts" @default.
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- W2004355321 doi "https://doi.org/10.1016/j.apcatb.2004.01.001" @default.
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