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- W2004357796 abstract "Three surfactants, with the same long alkyl tail but varying in functional groups, were selected to modify two pristine clays with different cation exchange capacities (CEC). Each of the modified clays was melt-mixed with polypropylene (PP) to prepare nanocomposites. The microstructure of the resultant nanocomposites was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and rheological techniques. The results showed that the surfactant structure had remarkable effects on the morphology and shear rheology of the nanocomposites based on the high-CEC organoclay: use of benzyl functional groups led to the highest extent of intercalation and highest enhancement of shear properties, while use of 2-hydroxyethyl groups had the opposite effect. Nanocomposites based on low-CEC organoclay all exhibited poor dispersion and their shear behavior was changed only slightly in comparison to the polymer matrix. In the case of extensional rheology, strain hardening was observed only in the two nanocomposites containing surfactants with 2-hydroxyethyl groups, regardless of the dispersion state of the nanoparticles." @default.
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- W2004357796 date "2015-01-27" @default.
- W2004357796 modified "2023-10-14" @default.
- W2004357796 title "Influence of Surfactant Functional Groups on Morphology and Rheology of Polypropylene/Organoclay Nanocomposites" @default.
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- W2004357796 doi "https://doi.org/10.1080/00222348.2015.1010424" @default.
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