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- W2004357965 abstract "The pH profile (log k vs. pH) of the reactions of poly-L-lysine (PL) with a series of aryl acetates and aryl methyl carbonates in aqueous solution show the same conformational changes as those determined by potentiometric titrations. When PL is a random coil, the most probable mechanism for the reactions studied is through the formation of a tetrahedral intermediate and its breakdown to products as the rate-determining step. The tetrahedral intermediate is stabilized by a hydrogen bond interaction between the nitro groups in the substrate and the NH group of the principal chain or some NH2 groups of the lateral chains. Copyright © 2007 John Wiley & Sons, Ltd." @default.
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- W2004357965 date "2007-12-04" @default.
- W2004357965 modified "2023-09-27" @default.
- W2004357965 title "Reaction of poly-L -lysine with aryl acetates and aryl methyl carbonates. A mechanistic study" @default.
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- W2004357965 doi "https://doi.org/10.1002/poc.1285" @default.
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