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- W2004358628 abstract "Methyl thiophene-2-carboxylate, methyl 3-(thien-2-yl)acrylate, and methyl 5,2'-bithiophene-2-carboxylate were utilized as the synthetic equivalents of pentanoate 5-anion, pentanoate 4,5-dianion, heptanoate 7-anion, and nonanoate-8,9-dianion. By the promotion of samarium diiodide, these thiophene-incorporating compounds reacted with aldehydes, ketones, and conjugated esters regioselectively at the thienyl rings. Long-chain esters with remote hydroxyl and carboxyl groups, including an antiarthritis agent, a shellac component, and an inhibitory agent of spore germination, were prepared after reductive desulfurization on Raney nickel." @default.
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- W2004358628 date "2001-04-03" @default.
- W2004358628 modified "2023-09-24" @default.
- W2004358628 title "ChemInform Abstract: Distant Functionalization via Incorporation of Thiophene Moieties in Electrophilic Reactions Promoted by Samarium Diiodide." @default.
- W2004358628 cites W2952917922 @default.
- W2004358628 doi "https://doi.org/10.1002/chin.200114077" @default.
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