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• W2004363576 abstract "1,1′-Bis(diphenylphosphino)ferrocene (dppf) reacted with RuCl(Ph3P)2Cp∗ to give RuCl(dppf)Cp∗ in good yield. The complex reacted with AgBF4 in acetonitrile to give [Ru(CH3CN) (dppf)Cp∗]BF4 quantitatively and in acetone to give [Ru(η2−O2) (dppf)Cp∗]BF4 in good yield. The structure of the latter was determined by X-ray analysis. (±)-BINAP and (±)-DIOP were reacted with [RuCl2Cp ∗]nZn to give RuCl[(±)-BINAP]Cp∗ and RuCl[(±)-DIOP]Cp∗ respectively, in moderate yields. They reacted with phenylacetylene in the presence of NH4PF6 to afford the corresponding RuII phenylacetylide complexes. The asymmetric condensation of phenylacetylene with allyl alcohol in the presence of these diphosphine complexes was unsuccessful." @default.
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• W2004363576 date "1996-02-01" @default.
• W2004363576 modified "2023-10-17" @default.
• W2004363576 title "Synthetic studies of permethylcyclopentadienyl ruthenium(II) complexes involving dppf, (±)-BINAP and (±)-DIOP ligands" @default.
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• W2004363576 doi "https://doi.org/10.1016/0022-328x(95)05782-k" @default.
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