Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004364095> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2004364095 endingPage "3655" @default.
- W2004364095 startingPage "3650" @default.
- W2004364095 abstract "The fractional change in the fluorescence yield ψF of TMPD in tetramethylsilane, due to imposition of an electric field of strength E=45.6 kV/cm, has been determined at 44 discrete excitation energies, ε, above the photoionization threshold from ε=4.77 to 7.52 eV. Two maxima are clearly resolved in the field quenching ratio, (ΔψF/ψF0)E, one at 5.71 eV and the other at 6.79 eV. Beyond 7.0 eV, (ΔψF/ψF0)E is again observed to slowly increase. For each of 12 of the previous excitation energies, (ΔψF/ψF0)E was obtained as a function of E from 18.2 to 45.6 kV/cm. Using an exponential radial distribution function of geminate pair separation distances, f(r)=β3e−βr/2, the field dependence was fitted to the Onsager theory and the average electron thermalization range, 〈r〉=3/β extracted as a function ε. With this, the yield of thermalized electrons, φ± was also obtained as a function of ε. The range spectrum is found to increase with increasing ε with an inflection at 5.9 eV, followed by a rapid rise to a maximum of 230 Å at 6.7 eV and then to decline continuously to 167 Å at 7.5 eV. The photoionization yield spectrum shows two maxima, one at 5.7 eV with φ±=0.44 and a second at 6.9 eV with φ±=0.52. Beyond 7.0 eV, φ± increases to 0.57 at ε=7.5 eV. It is concluded on the basis of an analysis of these spectra that photoionization of TMPD in tetramethylsilane from 5.9 to 7.5 eV generates in relatively high yield at least two electronically excited states of the positive ion." @default.
- W2004364095 created "2016-06-24" @default.
- W2004364095 creator A5010698953 @default.
- W2004364095 creator A5013527936 @default.
- W2004364095 date "1985-04-15" @default.
- W2004364095 modified "2023-10-16" @default.
- W2004364095 title "The photoionization yield and electron thermalization range spectra of <i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-tetramethyl-<i>p</i>-phenylenediamine (TMPD) in tetramethylsilane" @default.
- W2004364095 cites W1967269716 @default.
- W2004364095 cites W1969400967 @default.
- W2004364095 cites W1995593822 @default.
- W2004364095 cites W2000719277 @default.
- W2004364095 cites W2007882193 @default.
- W2004364095 cites W2019415151 @default.
- W2004364095 cites W2027949187 @default.
- W2004364095 cites W2029388300 @default.
- W2004364095 cites W2034588787 @default.
- W2004364095 cites W2041304190 @default.
- W2004364095 cites W2050587090 @default.
- W2004364095 cites W2051658943 @default.
- W2004364095 cites W2055866840 @default.
- W2004364095 cites W2058434846 @default.
- W2004364095 cites W2073078558 @default.
- W2004364095 cites W2082500208 @default.
- W2004364095 cites W2084929271 @default.
- W2004364095 cites W2090643039 @default.
- W2004364095 cites W2091372601 @default.
- W2004364095 cites W2949798226 @default.
- W2004364095 doi "https://doi.org/10.1063/1.448900" @default.
- W2004364095 hasPublicationYear "1985" @default.
- W2004364095 type Work @default.
- W2004364095 sameAs 2004364095 @default.
- W2004364095 citedByCount "26" @default.
- W2004364095 crossrefType "journal-article" @default.
- W2004364095 hasAuthorship W2004364095A5010698953 @default.
- W2004364095 hasAuthorship W2004364095A5013527936 @default.
- W2004364095 hasConcept C113196181 @default.
- W2004364095 hasConcept C121332964 @default.
- W2004364095 hasConcept C1276947 @default.
- W2004364095 hasConcept C145148216 @default.
- W2004364095 hasConcept C147120987 @default.
- W2004364095 hasConcept C155220765 @default.
- W2004364095 hasConcept C158749347 @default.
- W2004364095 hasConcept C178790620 @default.
- W2004364095 hasConcept C181500209 @default.
- W2004364095 hasConcept C184779094 @default.
- W2004364095 hasConcept C185592680 @default.
- W2004364095 hasConcept C198291218 @default.
- W2004364095 hasConcept C2778200147 @default.
- W2004364095 hasConcept C43617362 @default.
- W2004364095 hasConcept C4839761 @default.
- W2004364095 hasConcept C62520636 @default.
- W2004364095 hasConcept C83581075 @default.
- W2004364095 hasConceptScore W2004364095C113196181 @default.
- W2004364095 hasConceptScore W2004364095C121332964 @default.
- W2004364095 hasConceptScore W2004364095C1276947 @default.
- W2004364095 hasConceptScore W2004364095C145148216 @default.
- W2004364095 hasConceptScore W2004364095C147120987 @default.
- W2004364095 hasConceptScore W2004364095C155220765 @default.
- W2004364095 hasConceptScore W2004364095C158749347 @default.
- W2004364095 hasConceptScore W2004364095C178790620 @default.
- W2004364095 hasConceptScore W2004364095C181500209 @default.
- W2004364095 hasConceptScore W2004364095C184779094 @default.
- W2004364095 hasConceptScore W2004364095C185592680 @default.
- W2004364095 hasConceptScore W2004364095C198291218 @default.
- W2004364095 hasConceptScore W2004364095C2778200147 @default.
- W2004364095 hasConceptScore W2004364095C43617362 @default.
- W2004364095 hasConceptScore W2004364095C4839761 @default.
- W2004364095 hasConceptScore W2004364095C62520636 @default.
- W2004364095 hasConceptScore W2004364095C83581075 @default.
- W2004364095 hasIssue "8" @default.
- W2004364095 hasLocation W20043640951 @default.
- W2004364095 hasOpenAccess W2004364095 @default.
- W2004364095 hasPrimaryLocation W20043640951 @default.
- W2004364095 hasRelatedWork W1984164594 @default.
- W2004364095 hasRelatedWork W1987627399 @default.
- W2004364095 hasRelatedWork W1987911670 @default.
- W2004364095 hasRelatedWork W2011933939 @default.
- W2004364095 hasRelatedWork W2022060885 @default.
- W2004364095 hasRelatedWork W2052707055 @default.
- W2004364095 hasRelatedWork W2582682618 @default.
- W2004364095 hasRelatedWork W2890828271 @default.
- W2004364095 hasRelatedWork W2966965822 @default.
- W2004364095 hasRelatedWork W2973802118 @default.
- W2004364095 hasVolume "82" @default.
- W2004364095 isParatext "false" @default.
- W2004364095 isRetracted "false" @default.
- W2004364095 magId "2004364095" @default.
- W2004364095 workType "article" @default.