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- W2004377595 abstract "This article describes an organocatalytic, enantioselective α- arylation of aldehydes, in which quinones are applied as the aromatic partner, to afford optically active α-arylated aldehydes. Following the addition/aromatization sequence, subsequent hemiacetal formation affords the 2,3-dihydrobenzofuran products. The direct α-arylation consists of two catalytic cycles. The stereogenic center is formed in the first cycle - the reaction of the enamine intermediate with the quinone. In the second cycle a series of proton-transfer reactions leads to the optically active α-arylated aldehyde." @default.
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- W2004377595 date "2014-01-01" @default.
- W2004377595 modified "2023-09-26" @default.
- W2004377595 title "Enantioselective Organocatalytic α-Arylation of Aldehydes" @default.
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- W2004377595 doi "https://doi.org/10.15227/orgsyn.091.0175" @default.
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