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- W2004378622 abstract "The homogeneous reverse atom transfer radical polymerization (ATRP) of styrene was initiated by benzoyl peroxide (BPO) in the presence of CuBr or CuBr2 complexed by 4,4‘-di(5-nonyl)-2,2‘-bipyridine (dNbpy). In contrast to the successful reverse ATRP initiated by azobis(isobutyronitrile) (AIBN) and CuBr2/2dNbpy, no control of polymerization was observed for the BPO/CuBr2/2dNbpy system. However, controlled/“living” polymerization was observed when BPO was used together with CuBr/2dNbpy. The differences between the BPO and AIBN systems are ascribed to the electron transfer and the formation of copper benzoate species." @default.
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- W2004378622 date "1999-07-20" @default.
- W2004378622 modified "2023-10-14" @default.
- W2004378622 title "Homogeneous Reverse Atom Transfer Radical Polymerization of Styrene Initiated by Peroxides" @default.
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- W2004378622 doi "https://doi.org/10.1021/ma990036f" @default.
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