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- W2004389898 abstract "We study the classical statistical mechanics of a shell-model chain with a quartic electron-ion interaction in one ionic species. In order to avoid long-range interactions generated by the adiabatic treatment of the shells, we assign them a finite mass. Under integration of the harmonic degrees of freedom, the partition function is shown to correspond to an effective ${ensuremath{varphi}}^{4}$ model. This allows us to apply the transfer-integral technique for calculation of the free energy in the displacive limit. For the continuum we obtain exact kinktype solutions of the equations of motion. These excitations, together with phonons which represent oscillations about kink configurations, are considered as interacting quasiparticles for the construction of the free energy, thus reobtaining the exact results in the low-temperature limit. This approach allows the extension of our results to the adiabatic case." @default.
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- W2004389898 date "1988-08-01" @default.
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- W2004389898 title "Classical statistical mechanics of the nonlinearly polarizable shell-model chain for ferroelectric materials" @default.
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- W2004389898 doi "https://doi.org/10.1103/physrevb.38.2801" @default.
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