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- W2004396684 abstract "The kinetics and stoicheiometry of the decomposition of hydroxylamine in nitric acid have been investigated for the range of conditions where there is a change in function of hydroxylamine from acting as a nitrite scavenger to acting as a generator of nitrous acid. Borderline conditions for this change in function have been identified. Formation of nitrous acid is favoured by increase in [HNO3], decrease in [NH3OH+] and increase in temperature. Some unusual kinetic phenomena have been observed in the borderline region; the nitrous acid concentration can decrease in the initial stages of reaction, pass through a minimum and then autocatalytically increase to a value greater than the initial value. The results are discussed in terms of the mechanism of reaction." @default.
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- W2004396684 date "1981-01-01" @default.
- W2004396684 modified "2023-09-23" @default.
- W2004396684 title "Kinetic and product studies on the decomposition of hydroxylamine in nitric acid" @default.
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- W2004396684 doi "https://doi.org/10.1016/0022-1902(81)80631-8" @default.
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