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• W2004409840 endingPage "8723" @default.
• W2004409840 startingPage "8713" @default.
• W2004409840 abstract "Treatment of a series of dinuclear Ir(III) complexes [(fnazo)2Ir(μ-Cl]2, [(fpiq)2Ir(μ-Cl]2, and [(fppy)2Ir(μ-Cl]2 with diphenyl(1-naphthyl)phosphine (dpnH) in decalin at 100 °C afforded the simple adducts, trans-N,N′-[(fnazo)2Ir(dpnH)Cl] (1a), trans-N,N′-[(fpiq)2Ir(dpnH)Cl] (1b), and trans-N,N′-[(fppy)2Ir(dpnH)Cl] (1c), for which the C∧N cyclometalating reagents, that is, fnazoH, fpiqH and fppyH, stands for 4-(4-fluorophenyl)quinazoline, 1-(4-fluorophenyl)isoquinoline and 4-fluorophenylpyridine, respectively. Single crystal X-ray diffraction study on 1a revealed existence of two trans-N,N′ cyclometalates, with both chloride and dpnH donors located at the positions opposite to the phenyl substituents. Subsequent heating of 1a−1c at higher temperature afforded the second isomer (2a−2c), showing formation of cis-N,N′ orientation for the aforementioned cyclometalates. Further thermolysis of either trans or cis-Ir(III) complexes 1 or 2 in presence of sodium acetate, which serves as both activator and chloride scavenger, gave successful isolation of a mixture of two fully cyclometalated Ir(III) complexes trans-N,N′-[(C∧N)2Ir(dpn)] (3a−3c) and cis-N,N′-[(C∧N)2Ir(dpn)] (4a−4c). Structural and photophysical properties of complexes 3a−3c and 4a−4c were measured and compared. Time-dependent density functional theory (DFT) studies suggested that, upon changing the C∧N cyclometalates from quinazolinyl, isoquinolinyl, and, finally, to pyridyl fragment, the lowest unoccupied molecular orbitals (LUMOs) are gradually shifted from the cyclometalating nitrogen heterocycles to the 1-naphthyl group of the phosphine chelate and, concomitantly altered the photophysical properties. An organic light-emitting diode (OLED) using orange-red phosphors 4a and 4b has been successfully fabricated. At the practical brightness of 500 cd·m−2, decent external quantum efficiency of 10.6% and 12.5% could be reached for 4a and 4b, respectively, revealing the usefulness of relevant molecular architecture in designing triplet OLED emitters." @default.
• W2004409840 created "2016-06-24" @default.
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• W2004409840 date "2010-09-03" @default.
• W2004409840 modified "2023-09-23" @default.
• W2004409840 title "Diphenyl(1-naphthyl)phosphine Ancillary for Assembling of Red and Orange-Emitting Ir(III) Based Phosphors; Strategic Synthesis, Photophysics, and Organic Light-Emitting Diode Fabrication" @default.
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• W2004409840 doi "https://doi.org/10.1021/ic100935b" @default.
• W2004409840 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20815333" @default.
• W2004409840 hasPublicationYear "2010" @default.
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