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- W2004429689 abstract "Abstract Whereas the fusion of three-membered rings NB2R2R′ (1b-d; R = lsBu R’ = Me, Et, iPr ) gives diza-nido-hexaboranes N2B4R4R′2 (2b–d), the fusion of the corresponding 1e (R′ = CH2 tBu) yields the isomeric tetracyclic molecules 3e, which crystallizes in the space group P1. Two BN double bonds in 3 correspond to four BN single bonds in 2 and thus indicate a transformation ofn 3 into 2 via an antarafacial (2+2) cycloaddition. The isolation of 3e offers a mechanistic understanding of the fusion of 1 to give 2 via 3, including the observed stereospecificity." @default.
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- W2004429689 date "1998-03-01" @default.
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- W2004429689 title "Clusters N2B4R6 from the fusion of rings NB2R3: mechanism" @default.
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- W2004429689 doi "https://doi.org/10.1016/s0020-1693(97)05780-0" @default.
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