Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004430362> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2004430362 endingPage "5317" @default.
- W2004430362 startingPage "5311" @default.
- W2004430362 abstract "Reaction of [RhCl(NBD)]2 with 2.0 equiv of triphos (triphos = bis(2-diphenylphosphinoethyl)phenylphosphine; NBD = bicyclo[2.2.1]hepta-2,5-diene) in THF solution at room temperature affords [Rh(NBD)(triphos)][Cl] (4a), which was isolated as [Rh(NBD)(triphos)][SbF6] (4b) in 67% yield. Treatment of 4b with aqueous formaldehyde in THF solution at 80 °C forms [Rh(CO)(triphos)][SbF6] (2a), which reversibly binds a second equivalent of CO(g) to give [Rh(CO)2(triphos)][SbF6] (2b). The complex [Rh(CO)(triphos)][SbF6] has been found to be an effective aldehyde decarbonylation catalyst for primary and aryl aldehydes at temperatures as low as that of refluxing dioxane, with little or no undesirable side products resulting from β elimination or radical rearrangement." @default.
- W2004430362 created "2016-06-24" @default.
- W2004430362 creator A5003058962 @default.
- W2004430362 creator A5041578473 @default.
- W2004430362 creator A5057022478 @default.
- W2004430362 creator A5057803757 @default.
- W2004430362 creator A5063732113 @default.
- W2004430362 creator A5074404511 @default.
- W2004430362 creator A5090136280 @default.
- W2004430362 date "1999-11-17" @default.
- W2004430362 modified "2023-10-17" @default.
- W2004430362 title "Aldehyde Decarbonylation Catalysis under Mild Conditions" @default.
- W2004430362 cites W106300948 @default.
- W2004430362 cites W107426042 @default.
- W2004430362 cites W1968795929 @default.
- W2004430362 cites W2031551928 @default.
- W2004430362 cites W2032449072 @default.
- W2004430362 cites W2039582846 @default.
- W2004430362 cites W2040895704 @default.
- W2004430362 cites W2053203724 @default.
- W2004430362 cites W2061534958 @default.
- W2004430362 cites W2065948329 @default.
- W2004430362 cites W2166339263 @default.
- W2004430362 cites W2949083805 @default.
- W2004430362 cites W2949765815 @default.
- W2004430362 cites W2951874605 @default.
- W2004430362 cites W2953380236 @default.
- W2004430362 doi "https://doi.org/10.1021/om9905106" @default.
- W2004430362 hasPublicationYear "1999" @default.
- W2004430362 type Work @default.
- W2004430362 sameAs 2004430362 @default.
- W2004430362 citedByCount "147" @default.
- W2004430362 countsByYear W20044303622012 @default.
- W2004430362 countsByYear W20044303622013 @default.
- W2004430362 countsByYear W20044303622014 @default.
- W2004430362 countsByYear W20044303622015 @default.
- W2004430362 countsByYear W20044303622016 @default.
- W2004430362 countsByYear W20044303622017 @default.
- W2004430362 countsByYear W20044303622018 @default.
- W2004430362 countsByYear W20044303622019 @default.
- W2004430362 countsByYear W20044303622020 @default.
- W2004430362 countsByYear W20044303622021 @default.
- W2004430362 countsByYear W20044303622022 @default.
- W2004430362 countsByYear W20044303622023 @default.
- W2004430362 crossrefType "journal-article" @default.
- W2004430362 hasAuthorship W2004430362A5003058962 @default.
- W2004430362 hasAuthorship W2004430362A5041578473 @default.
- W2004430362 hasAuthorship W2004430362A5057022478 @default.
- W2004430362 hasAuthorship W2004430362A5057803757 @default.
- W2004430362 hasAuthorship W2004430362A5063732113 @default.
- W2004430362 hasAuthorship W2004430362A5074404511 @default.
- W2004430362 hasAuthorship W2004430362A5090136280 @default.
- W2004430362 hasConcept C132190689 @default.
- W2004430362 hasConcept C161790260 @default.
- W2004430362 hasConcept C178790620 @default.
- W2004430362 hasConcept C185592680 @default.
- W2004430362 hasConcept C2779825165 @default.
- W2004430362 hasConceptScore W2004430362C132190689 @default.
- W2004430362 hasConceptScore W2004430362C161790260 @default.
- W2004430362 hasConceptScore W2004430362C178790620 @default.
- W2004430362 hasConceptScore W2004430362C185592680 @default.
- W2004430362 hasConceptScore W2004430362C2779825165 @default.
- W2004430362 hasIssue "25" @default.
- W2004430362 hasLocation W20044303621 @default.
- W2004430362 hasOpenAccess W2004430362 @default.
- W2004430362 hasPrimaryLocation W20044303621 @default.
- W2004430362 hasRelatedWork W1970106510 @default.
- W2004430362 hasRelatedWork W2047888616 @default.
- W2004430362 hasRelatedWork W2343368380 @default.
- W2004430362 hasRelatedWork W2407460809 @default.
- W2004430362 hasRelatedWork W2949469610 @default.
- W2004430362 hasRelatedWork W2950375547 @default.
- W2004430362 hasRelatedWork W2951723436 @default.
- W2004430362 hasRelatedWork W2952812240 @default.
- W2004430362 hasRelatedWork W2953114251 @default.
- W2004430362 hasRelatedWork W3023161512 @default.
- W2004430362 hasVolume "18" @default.
- W2004430362 isParatext "false" @default.
- W2004430362 isRetracted "false" @default.
- W2004430362 magId "2004430362" @default.
- W2004430362 workType "article" @default.