FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004440823> ?p ?o ?g. }

• W2004440823 abstract "Dicarbonyl(η5-cyclopentadienyl)(trimethylsilyl)iron (1) was found to react with a 1 M solution of tetrabutylammonium fluoride (2) in tetrahydrofuran at 25°C to give dicarbonyl(η5-cyclopentadienyl)iron anion (5). The anion generated under these conditions was trapped with electrophiles (RX) to give 45–89% yields of neutral dicarbonyl(η5-cyclopentadienyl)-alkyl, -allyl, -acyl-iron compounds and the ethylene cation. Tetrabutylammonium hydroxide also can be used in this reaction. Evidence indicates that fluoride ion instead of hydroxide attacks the silicon when tetrabutylammonium fluoride is used since fluorotrimethylsilane can be detected in the reaction product. Tetrabutylammonium fluoride and hydroxide quantitatively liberate styrene from dicarbonyl(η5-cyclopentadienyl)(η2-styrene)iron tetrafluoroborate, producing bis[dicarbonyl(η2-cyclopentadienyl)iron]." @default.
• W2004440823 created "2016-06-24" @default.
• W2004440823 creator A5068007467 @default.
• W2004440823 creator A5078817162 @default.
• W2004440823 date "1983-07-01" @default.
• W2004440823 modified "2023-09-27" @default.
• W2004440823 title "Ironsilicon bond cleavage in dicarbonyl(ν5-cyclopentadienyl)(trimethylsilyl)iron using tetrabutylammonium fluoride" @default.
• W2004440823 cites W1538316828 @default.
• W2004440823 cites W1966544640 @default.
• W2004440823 cites W1966649585 @default.
• W2004440823 cites W1976600524 @default.
• W2004440823 cites W1977247189 @default.
• W2004440823 cites W1992200435 @default.
• W2004440823 cites W2007148355 @default.
• W2004440823 cites W2017285404 @default.
• W2004440823 cites W2022750593 @default.
• W2004440823 cites W2023471995 @default.
• W2004440823 cites W2029234883 @default.
• W2004440823 cites W2033442981 @default.
• W2004440823 cites W2038533659 @default.
• W2004440823 cites W2057414886 @default.
• W2004440823 cites W2085871069 @default.
• W2004440823 cites W2089081331 @default.
• W2004440823 cites W2100163409 @default.
• W2004440823 cites W2105016564 @default.
• W2004440823 cites W2112705632 @default.
• W2004440823 cites W2157202805 @default.
• W2004440823 cites W2323196669 @default.
• W2004440823 cites W2327502678 @default.
• W2004440823 cites W2942492654 @default.
• W2004440823 cites W2949548980 @default.
• W2004440823 cites W2949558983 @default.
• W2004440823 cites W3137657172 @default.
• W2004440823 doi "https://doi.org/10.1016/0022-328x(83)80245-9" @default.
• W2004440823 hasPublicationYear "1983" @default.
• W2004440823 type Work @default.
• W2004440823 sameAs 2004440823 @default.
• W2004440823 citedByCount "6" @default.
• W2004440823 crossrefType "journal-article" @default.
• W2004440823 hasAuthorship W2004440823A5068007467 @default.
• W2004440823 hasAuthorship W2004440823A5078817162 @default.
• W2004440823 hasConcept C154881586 @default.
• W2004440823 hasConcept C155647269 @default.
• W2004440823 hasConcept C15920480 @default.
• W2004440823 hasConcept C161790260 @default.
• W2004440823 hasConcept C178790620 @default.
• W2004440823 hasConcept C179104552 @default.
• W2004440823 hasConcept C181458950 @default.
• W2004440823 hasConcept C185592680 @default.
• W2004440823 hasConcept C188027245 @default.
• W2004440823 hasConcept C2775896084 @default.
• W2004440823 hasConcept C2776701986 @default.
• W2004440823 hasConcept C2777000832 @default.
• W2004440823 hasConcept C2777566558 @default.
• W2004440823 hasConcept C2780239050 @default.
• W2004440823 hasConcept C2780471494 @default.
• W2004440823 hasConcept C2780828025 @default.
• W2004440823 hasConcept C2780872544 @default.
• W2004440823 hasConcept C2910812283 @default.
• W2004440823 hasConcept C50027330 @default.
• W2004440823 hasConcept C521977710 @default.
• W2004440823 hasConceptScore W2004440823C154881586 @default.
• W2004440823 hasConceptScore W2004440823C155647269 @default.
• W2004440823 hasConceptScore W2004440823C15920480 @default.
• W2004440823 hasConceptScore W2004440823C161790260 @default.
• W2004440823 hasConceptScore W2004440823C178790620 @default.
• W2004440823 hasConceptScore W2004440823C179104552 @default.
• W2004440823 hasConceptScore W2004440823C181458950 @default.
• W2004440823 hasConceptScore W2004440823C185592680 @default.
• W2004440823 hasConceptScore W2004440823C188027245 @default.
• W2004440823 hasConceptScore W2004440823C2775896084 @default.
• W2004440823 hasConceptScore W2004440823C2776701986 @default.
• W2004440823 hasConceptScore W2004440823C2777000832 @default.
• W2004440823 hasConceptScore W2004440823C2777566558 @default.
• W2004440823 hasConceptScore W2004440823C2780239050 @default.
• W2004440823 hasConceptScore W2004440823C2780471494 @default.
• W2004440823 hasConceptScore W2004440823C2780828025 @default.
• W2004440823 hasConceptScore W2004440823C2780872544 @default.
• W2004440823 hasConceptScore W2004440823C2910812283 @default.
• W2004440823 hasConceptScore W2004440823C50027330 @default.
• W2004440823 hasConceptScore W2004440823C521977710 @default.
• W2004440823 hasLocation W20044408231 @default.
• W2004440823 hasOpenAccess W2004440823 @default.
• W2004440823 hasPrimaryLocation W20044408231 @default.
• W2004440823 hasRelatedWork W1502763385 @default.
• W2004440823 hasRelatedWork W1536800469 @default.
• W2004440823 hasRelatedWork W1602920784 @default.
• W2004440823 hasRelatedWork W1627713894 @default.
• W2004440823 hasRelatedWork W1969132898 @default.
• W2004440823 hasRelatedWork W1969459194 @default.
• W2004440823 hasRelatedWork W1980044498 @default.
• W2004440823 hasRelatedWork W1995388820 @default.
• W2004440823 hasRelatedWork W2071706167 @default.
• W2004440823 hasRelatedWork W2072043000 @default.
• W2004440823 hasRelatedWork W2091051769 @default.
• W2004440823 hasRelatedWork W2138322257 @default.
• W2004440823 hasRelatedWork W2141799590 @default.
• W2004440823 hasRelatedWork W2284816298 @default.
• W2004440823 hasRelatedWork W2390453976 @default.
• W2004440823 hasRelatedWork W2952225241 @default.

• next