Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004454974> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2004454974 endingPage "432" @default.
- W2004454974 startingPage "417" @default.
- W2004454974 abstract "A product resulting from cleavage of the PC bond in a trimethylphosphine ligand forms upon thermolysis of (PMe3)4Ru(OC6H4Me)2 (1) or addition of p-cresol to the orthometallated complex (PMe3)4Ru(η2-OC6H3Me) (2). The trimethylphosphine ligand has been transformed to a dimethylarylphosphinite ligand in the product (PMe3)3(η2-PMe2OC6H3)Ru(OC6H4Me) (3). Although complex 1 exists in equilibrium with complex 2 and free p-cresol at 65° C, kinetic evidence is presented indicating that complex 1 undergoes the PC cleavage reaction. An X-ray crystal structure analysis was performed on 3. Crystal data at 25° C: a 11.8875(11), b 36.000(4), c 14.1207(13) Å, β = 90.428(8)°, Z = 8, Dcalc 1.33 g/cm3; space group P21/n." @default.
- W2004454974 created "2016-06-24" @default.
- W2004454974 creator A5035244196 @default.
- W2004454974 creator A5047518475 @default.
- W2004454974 creator A5088865204 @default.
- W2004454974 date "1990-08-01" @default.
- W2004454974 modified "2023-10-18" @default.
- W2004454974 title "A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2" @default.
- W2004454974 cites W1020012471 @default.
- W2004454974 cites W1964544316 @default.
- W2004454974 cites W1977870734 @default.
- W2004454974 cites W1980061049 @default.
- W2004454974 cites W1995125797 @default.
- W2004454974 cites W1995807576 @default.
- W2004454974 cites W2003803740 @default.
- W2004454974 cites W2005501192 @default.
- W2004454974 cites W2011193606 @default.
- W2004454974 cites W2020610877 @default.
- W2004454974 cites W2038546150 @default.
- W2004454974 cites W2061185014 @default.
- W2004454974 cites W2065905951 @default.
- W2004454974 cites W2069481759 @default.
- W2004454974 cites W2073186142 @default.
- W2004454974 cites W2073227811 @default.
- W2004454974 cites W2074664376 @default.
- W2004454974 cites W2081120261 @default.
- W2004454974 cites W2091702998 @default.
- W2004454974 cites W2093175524 @default.
- W2004454974 cites W2125112479 @default.
- W2004454974 cites W273342346 @default.
- W2004454974 cites W2951799167 @default.
- W2004454974 doi "https://doi.org/10.1016/0022-328x(90)87247-b" @default.
- W2004454974 hasPublicationYear "1990" @default.
- W2004454974 type Work @default.
- W2004454974 sameAs 2004454974 @default.
- W2004454974 citedByCount "27" @default.
- W2004454974 countsByYear W20044549742013 @default.
- W2004454974 countsByYear W20044549742014 @default.
- W2004454974 countsByYear W20044549742015 @default.
- W2004454974 crossrefType "journal-article" @default.
- W2004454974 hasAuthorship W2004454974A5035244196 @default.
- W2004454974 hasAuthorship W2004454974A5047518475 @default.
- W2004454974 hasAuthorship W2004454974A5088865204 @default.
- W2004454974 hasConcept C115624301 @default.
- W2004454974 hasConcept C116569031 @default.
- W2004454974 hasConcept C127413603 @default.
- W2004454974 hasConcept C155647269 @default.
- W2004454974 hasConcept C160434732 @default.
- W2004454974 hasConcept C161790260 @default.
- W2004454974 hasConcept C170493617 @default.
- W2004454974 hasConcept C175156509 @default.
- W2004454974 hasConcept C178790620 @default.
- W2004454974 hasConcept C185592680 @default.
- W2004454974 hasConcept C187320778 @default.
- W2004454974 hasConcept C2775968720 @default.
- W2004454974 hasConcept C3044715 @default.
- W2004454974 hasConcept C43369102 @default.
- W2004454974 hasConcept C55493867 @default.
- W2004454974 hasConcept C8010536 @default.
- W2004454974 hasConceptScore W2004454974C115624301 @default.
- W2004454974 hasConceptScore W2004454974C116569031 @default.
- W2004454974 hasConceptScore W2004454974C127413603 @default.
- W2004454974 hasConceptScore W2004454974C155647269 @default.
- W2004454974 hasConceptScore W2004454974C160434732 @default.
- W2004454974 hasConceptScore W2004454974C161790260 @default.
- W2004454974 hasConceptScore W2004454974C170493617 @default.
- W2004454974 hasConceptScore W2004454974C175156509 @default.
- W2004454974 hasConceptScore W2004454974C178790620 @default.
- W2004454974 hasConceptScore W2004454974C185592680 @default.
- W2004454974 hasConceptScore W2004454974C187320778 @default.
- W2004454974 hasConceptScore W2004454974C2775968720 @default.
- W2004454974 hasConceptScore W2004454974C3044715 @default.
- W2004454974 hasConceptScore W2004454974C43369102 @default.
- W2004454974 hasConceptScore W2004454974C55493867 @default.
- W2004454974 hasConceptScore W2004454974C8010536 @default.
- W2004454974 hasIssue "1-3" @default.
- W2004454974 hasLocation W20044549741 @default.
- W2004454974 hasOpenAccess W2004454974 @default.
- W2004454974 hasPrimaryLocation W20044549741 @default.
- W2004454974 hasRelatedWork W1983134576 @default.
- W2004454974 hasRelatedWork W2016927307 @default.
- W2004454974 hasRelatedWork W2034034841 @default.
- W2004454974 hasRelatedWork W2041915051 @default.
- W2004454974 hasRelatedWork W2053825085 @default.
- W2004454974 hasRelatedWork W2099786662 @default.
- W2004454974 hasRelatedWork W2139783973 @default.
- W2004454974 hasRelatedWork W2371166865 @default.
- W2004454974 hasRelatedWork W2950156955 @default.
- W2004454974 hasRelatedWork W2966965872 @default.
- W2004454974 hasVolume "394" @default.
- W2004454974 isParatext "false" @default.
- W2004454974 isRetracted "false" @default.
- W2004454974 magId "2004454974" @default.
- W2004454974 workType "article" @default.