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• W2004457075 abstract "The preparation of two new bis(N-heterocyclic carbene) platinum(II) complexes, in which NHC rings are joined by a CH2 linker group, is described. While, the chelate complex [PtMe2(bis-NHC1)], 1, was formed with large tert-butyl wingtips, the iso-propylN-substituent analogue favors formation of the cluster complex [Pt2Me4(μ-SMe2)(μ-bis-NHC2)]2(μ-Ag2Br2), 2, in which two binuclear platinum(II) complexes are linked together by an Ag2Br2 unit. The chelating platinum complex 1 undergoes aerial CO2 fixation and forms platinum(II) carbonate complex [Pt(CO3)(bis-NHC1)], 3." @default.
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• W2004457075 date "2011-01-01" @default.
• W2004457075 modified "2023-10-09" @default.
• W2004457075 title "Organoplatinum(ii) complexes containing chelating or bridging bis(N-heterocyclic carbene) ligands: formation of a platinum(ii) carbonate complex by aerial CO2 fixation" @default.
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• W2004457075 doi "https://doi.org/10.1039/c1dt10736d" @default.
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