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- W2004465243 abstract "Abstract Cobalt(III) complexes of N,N′ -dimethylethylenediamine- N,N′ -diacetic acid (dmedda) and trifunctional amino acids, [Co(dmedda)(aa)] (aa=S-methyl- L-crysteine, L-glutamic acid, L-aspartic acid) have been prepared from the reaction between the s- cis - [Co(dmedda)Cl 2 ] − complex and the amino acid. The amino acids have been found to coordinate through the amine and carboxylate groups. The glutamic acid and aspartic acid are coordinated to the cobalt(III) ion via formation of the five- membered glycinate chelate ring. The optically active amino acids have shown a remarkable stereo- selectivity in their coordination to the racemic s- cis - [Co(dmedda)Cl 2 ] − giving the ▵-s- cis -[Co- (dmedda)(aa)] absolute configuration only." @default.
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- W2004465243 date "1988-05-01" @default.
- W2004465243 modified "2023-09-26" @default.
- W2004465243 title "Trifunctional amino acid-cobalt(III) complexes of N, N′-dimethylethylenediamine-N,N′-diacetic acid" @default.
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- W2004465243 doi "https://doi.org/10.1016/s0020-1693(00)83955-9" @default.
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