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- W2004475362 abstract "Quadrupole hyperfine structure has been observed in the v6RQ3(6) transition of 12CH335Cl using a stable CO2 laser oscillating on the 9.4 μm P(26) line. By heterodyning this laser with another which is locked to the 4.3 μm fluorescence dip of the 0001-000 CO2 transition, an accurate measurement of the hyperfine splittings has been made. The observed spectrum agrees, within experimental error, to the theoretical values evaluated without the need for a vibrational correction to the quadrupole interaction in the excited vibrational state. The hyperfine component closest to the center of the CO2 P(26) transition is determined to be 5.6 ± 0.1 MHz from the P(26) line center." @default.
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- W2004475362 date "1973-02-01" @default.
- W2004475362 modified "2023-10-17" @default.
- W2004475362 title "Observation of quadrupole hyperfine structure in the v6 RQ3 (6) transition of 12CH335Cl" @default.
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- W2004475362 doi "https://doi.org/10.1016/0009-2614(73)80196-4" @default.
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