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- W2004503271 abstract "Gliotoxin, C13H1404N2S2, a fungal product from Gliocladium fimbriatum, crystallizes in the monoclinic system with a= 10.17, b= 7.49, c= 18-28 A,, fl= 100.7 ° (at 150°C), Z=4. The space group being P2x, there are two independent molecules in the asymmetric unit. The structure was determined with data (2856 reflexions) from Weissenberg photographs of 6 layers around the b axis and 7 layers around the a axis by means of a three-dimensional Patterson distribution and a Fourier synthesis, and refined by full-matrix least-squares calculations and difference syntheses to R--0.088. The skeletal structure consists of a disulphide-bridged piperazinedione system linked through a five-membered pyrrolidinetype ring to a cyclohexadiene ring and three side groups of-CH3, -CHEOH and -OH. The absolute configuration has been determined by the use of the anomalous dispersion of the sulphur atoms, establishing the chirality of the skew diene chromophore and of the disulphide bridge." @default.
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- W2004503271 date "1967-09-10" @default.
- W2004503271 modified "2023-10-03" @default.
- W2004503271 title "The crystal structure of gliotoxin" @default.
- W2004503271 doi "https://doi.org/10.1107/s0365110x67002944" @default.
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