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- W2004507666 abstract "From e.m.f. measurements of the cell: Pt|CdxHg1−x|CdCl2,aq, m = 0.1 mol kg−|AgCl|Ag|Pt over the temperature range from 288.15 to 308.15 K, the standard potential of the cadmium-amalgam electrode has been determined, which can be reproduced by the equation: E°Cd + HgV = −0.3736907 − 2.099557 × 10−5(TK)2. The parallel values of the standard potential of the cadmium electrode have also been recalculated from data in the literature and have been found to be representable by E°CdV = −0.1991361 − 1.29106×−3(TK)+2.099557×10−6(TK)2. From ECd + Hgo and ECdo have been determined the standard thermodynamic functions at 298.15 K for the cadmium amalgamation reaction and for the species: cadmium amalgam, CdCl2(aq) and Cd2+(aq). Dilute cadmium amalgams behave as regular solutions as substantiated by the linear relation between the logarithm of the rational activity coefficient of cadmium in amalgam and the corresponding mole fraction: log10ƒCd = Qx, where in turn the parameter Q is a linear function of temperature: Q = 0.039362+8.3999×10−4(TK)." @default.
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- W2004507666 date "1979-04-01" @default.
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- W2004507666 title "Thermodynamics of the cadmium-amalgam electrode in aqueous medium" @default.
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- W2004507666 doi "https://doi.org/10.1016/0021-9614(79)90056-9" @default.
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