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- W2004544181 abstract "Scanning tunneling microscopy was used to study the initial stages of $mathrm{Cl}{}_{2}$ adsorption on $mathrm{TiO}{}_{2}(110)$. Cl atoms adsorb on the rows of fivefold coordinated surface Ti atoms, and mostly form well separated pairs (average distance $26AA{}$, atoms can be two or three rows apart). Abstractive adsorption results in 10% single Cl adatoms. We propose that $mathrm{Cl}{}_{2}$ dissociates in an approximately upright position. The outer Cl atom is emitted along the bond axis and can surmount the substrate bridging oxygen rows in a ``cannon-ball''-like trajectory. Channeling along the Ti rows leads to large average Cl-Cl distances." @default.
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- W2004544181 date "1998-07-13" @default.
- W2004544181 modified "2023-09-26" @default.
- W2004544181 title "High Transient Mobility of Chlorine on<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi>TiO</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>(</mml:mo><mml:mn>110</mml:mn><mml:mo>)</mml:mo></mml:math>: Evidence for ``Cannon-Ball'' Trajectories of Hot Adsorbates" @default.
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- W2004544181 doi "https://doi.org/10.1103/physrevlett.81.405" @default.
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