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- W2004550783 abstract "Abstract Heat capacity measurements have been made on diammonim dicadmium sulfate (ACdS), (NH4)2CD2(SO4)3, from 12 to 333 K in an adiabatic calorimeter. The transition into the ferroelectric phase near 92 K was observed as a sharp peak in the head capacity curve. Additional maxima in the form of a smaller peak at 90.7 K and a shoulder at 91.5 K were also detected and were attributed to sample inhomogeneities. The enthalpy and entropy of transition are (771±7) J.mol−1 and (8.4 ± 0.1 J.K−1.mol−1, respectively. No anomalous heat capacity was observed in the region of 162 K where other investigatore reported a phase transition, however. Smoothed values of the heat capacity, entropy, enthalpy increment, and Gibbs energy function are presented from 15 to 320 K. The thermodynamic results for the transition are discussed and compared to those from other ammonium langbeinites." @default.
- W2004550783 created "2016-06-24" @default.
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- W2004550783 date "1992-07-01" @default.
- W2004550783 modified "2023-09-25" @default.
- W2004550783 title "Heat capacity studies of phase transitions in langbeinites III. Diammonium dicadmium sulfate (NH4)2CD2(SO4)3" @default.
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- W2004550783 doi "https://doi.org/10.1080/00150199208009079" @default.
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