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• W2004554219 abstract "We report the synthesis, characterization and applications of a ruthenium–bipyridine based caged nicotine. The complex [Ru(bpy)2(nic)2]2+ (where bpy = 2,2′ bipyridine and nic = nicotine (3-[(2S)-1-methylpyrrolidin-2-yl] pyridine)) releases nicotine with a quantum yield ϕ = 0.23 upon irradiation with biologically harmless, blue (473 nm) or green (532 nm) light. The photolysis reaction is clean and very fast, with a time constant of 17 ns. The synthesis is simple and the obtained compound is characterized by NMR, UV-Vis spectroscopy and cyclic voltametry. We find that this compound is active in biological systems, being able to elicit action potentials in leech neurons." @default.
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• W2004554219 date "2010-12-01" @default.
• W2004554219 modified "2023-10-07" @default.
• W2004554219 title "A caged nicotine with nanosecond range kinetics and visible light sensitivity" @default.
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• W2004554219 doi "https://doi.org/10.1016/j.jinorgbio.2010.08.003" @default.
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