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- W2004595951 abstract "Abstract In this study, two perimidinium derivatives ( 1 and 2 ) were designed, synthesized, and developed as efficient fluorescent and colorimetric chemodosisensors for F − in DMSO or more competitive media (DMSO containing 10 % water). In the presence of F − , the yellow and non‐fluorescent solution of 1/2 became colourless and exhibited strong blue fluorescence. This unique spectroscopic behaviour of 1/2 towards F − was attributed to the formation of N‐heterocyclic carbene deprotonated by F − , which immediately reacted with water to give a colourless and fluorescent carbinol. Interestingly, it was found that this carbinol intermediate was unstable and further underwent a redox disproportionation to generate two other optically changed compounds. All the proposed mechanisms for the sensing process have been carefully confirmed by experiments." @default.
- W2004595951 created "2016-06-24" @default.
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- W2004595951 date "2014-10-24" @default.
- W2004595951 modified "2023-10-18" @default.
- W2004595951 title "N-Heterocyclic Carbene Formation Induced Fluorescent and Colorimetric Sensing of Fluoride Using Perimidinium Derivatives" @default.
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- W2004595951 doi "https://doi.org/10.1002/chem.201404806" @default.
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