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- W2004605004 abstract "The changes of microstructure occurring during oxidation of the reduced form of yttrium-doped barium titanate (Ba1-xYxTi1-x4+Tix3+O3) have been studied. Samples were sintered under reduction conditions at PO2=10-4Pa and oxidized by annealing at high temperatures (1150 and 1350 °C) in air. Depending on yttrium concentration, the oxidation of the reduced form of the yttrium-doped BaTiO3 caused precipitation of the phase Ba6Ti17O40 or the phases Ba6Ti17O40 and Y2Ti2O7. The precipitates had well-defined orientational relationships with the perovskite matrix. Oxidation of the reduced form of doped barium titanate results in formation of the phase Ba1-xYxTi1-x/44+(VTi⁗)x/4O3 responsible for increase in the resistance of outer grain layers, which lie between grain boundaries and grain." @default.
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- W2004605004 date "2005-05-01" @default.
- W2004605004 modified "2023-09-27" @default.
- W2004605004 title "Redox processes in highly yttrium-doped barium titanate" @default.
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- W2004605004 doi "https://doi.org/10.1016/j.jssc.2005.01.014" @default.
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