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- W2004605443 abstract "The Re(I) complexes bearing 2,6-bis(7 ′ -azaindolyl)phenyl group as a tridentate ligand were synthesized. The structures of the complexes were confirmed by X-ray crystallography. Green emission ( λ em =510 nm) was observed in THF solution at room temperature, which is considered to be attributable to MLCT (d z 2 (Re)→π * (7 ′ -azaindolyl group)) transition. The Re(I) complexes bearing 2,6-bis(7 ′ -azaindolyl)phenyl ligand as a tridentate ligand were synthesized by treatment with Re 2 (CO) 10 . The structures of the complexes were confirmed by X-ray crystallography. Both 7-azaindolyl ligands of Re(I) complexes are present in butterfly forms. The Re–C ipso bonds showed a partial double bond character by π back-donation between the phenyl moiety and Re atom. In THF solution at room temperature, these complexes exhibited green emission ( λ em =510 nm), which is considered to be attributable to MLCT (dz 2 (Re) →π * (7 ′ -azaindolyl group)) transition containing π→π * (7 ′ -azaindolyl group) transition." @default.
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- W2004605443 date "2004-05-01" @default.
- W2004605443 modified "2023-09-24" @default.
- W2004605443 title "Synthesis of Re(I) complexes bearing tridentate 2,6-bis(7′-azaindolyl)phenyl ligand with green emission properties" @default.
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- W2004605443 doi "https://doi.org/10.1016/j.jorganchem.2004.02.023" @default.
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