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- W2004643288 abstract "Abstract Die Verbindungen (CO) 5 Cr·S(R)Sn(CH 3 ) 3 ( 1, 2 ) lassen sich photochemisch aus Cr(CO) 6 und dem Liganden bereiten. Ihre Umsetzung mit elementorganischen Substraten R n EY (Y = Alkyl oder Halogen) überführt sie in Komplexe (CO) 5 Cr·S(R)ER n ( 3–9 ) mit E = Li, Mg, B, C, P, As, S; mit organometallischen Halogeniden des Goldes, Eisens, Mangans und Rheniums erhält man neue Übergangsmetall‐Schwefel‐Komplexe ( 10–15 ). Chemische und spektroskopische Studien zeigen, daß für E = P oder As die Cr(CO) 5 ‐Gruppe an diese Elemente und nicht an den Schwefel gebunden ist." @default.
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- W2004643288 date "1970-11-01" @default.
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- W2004643288 title "Metallorganische Lewis‐Basen, I. Elementorganische Mercaptide als Liganden in Pentacarbonylchrom(0)‐Komplexen" @default.
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