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• W2004659246 abstract "Abstract The intermolecular electron transfer reaction between a biphenyl anion and pyrene in supercritical ethane was studied using pulse radiolysis. Second-order electron transfer rates were found to be of the order of 1011 M−1 s−1. The rate constants appear to be approximately constant over the pressure range 55–133 bar and slower than the predicted diffusion-controlled rate constants. Two possibilities are discussed that could explain the present results: diffusion constants that are not well predicted by the hydrodynamic equation; or a solvent reorganization energy of approximately 0.35 eV and dependent on pressure. The reorganization energy Er of non-polar supercritical ethane was estimated from the observed rate constant using the modified Marcus equation. Er may be larger than normally expected for non-polar solvents because of density fluctuations." @default.
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• W2004659246 date "1998-06-01" @default.
• W2004659246 modified "2023-09-23" @default.
• W2004659246 title "Solvent reorganization energies measured by an electron transfer reaction in supercritical ethane" @default.
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• W2004659246 doi "https://doi.org/10.1016/s0896-8446(98)00047-3" @default.
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