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- W2004668828 abstract "Interaction of H2 with P2PdX2 complex (P = PPh3, X = CF3COO) in aqueous trifluoroacetic acid solution at 70°C in excess triphenylphosphine results in the formation of the palladium hydride complex [P3PdH]+. The same complex is formed by protonation of PdP4 at 25°C in aqueous CF3COOH. When treated by carbon monoxide, [P3RdH]+ is changed to the binuclear palladium carbonyl hydride complex [P2Pd(μ-H)(μ-CO)PdP2]+." @default.
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- W2004668828 date "1985-07-01" @default.
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- W2004668828 title "Formation and reactivity of palladium hydride complexes, [(PPh3)3PdH]+ and [(PPh3)2Pd(μ-H)(μ-CO)Pd(PPh3)2]+, in aqueous trifluoroacetic acid solutions" @default.
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- W2004668828 doi "https://doi.org/10.1016/0022-328x(85)87419-2" @default.
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