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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004670843> ?p ?o ?g. }

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• W2004670843 abstract "A flexible and robust method for the assembly of (1-->6)-linked C-glycosidic disaccharides is presented. The key reaction is a Pd-catalyzed coupling of 1-iodo- or 1-triflato-glycals with alkynyl glycosides. Reinstallation of the native hydroxyl group pattern is achieved after selective hydrogenation of the triple bond using Raney-nickel. Epoxidation with DMDO and reductive epoxide opening gives access to either the alpha- or the beta-derivative, depending on the hydride source." @default.
• W2004670843 created "2016-06-24" @default.
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• W2004670843 date "2010-08-05" @default.
• W2004670843 modified "2023-09-30" @default.
• W2004670843 title "A Pd-Catalyzed Approach to (1→6)-Linked <i>C</i>-Glycosides" @default.
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• W2004670843 doi "https://doi.org/10.1021/ol101625p" @default.
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