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- W2004683810 abstract "Abstract The Nagle-Morowitz proton pump, which is based on proton transport in water and ice, is shown to be inapplicable to weakly H-bonded proton transport systems. It is demonstrated that in weakly or non H-bonded systems protons can migrate either as excess protons H♭ using a high-lying proton conduction band or as defect protons H′ using intermediate energy levels. As H′ the protons act as positive charge carriers endowed with a very high mobility. As H′ they act as negative charge carriers. The H′ transport mechanism involves thermally activated proton tunneling. Owing to the very large mobility differences between H • and H′, > 10 6 , very high potentials can be self-generated in any situation which creates a concentration gradient. Proton conductivity data on inorganic model compounds are presented. Applying these results to proton transport across biomembranes, transmembrane potentials U m , acidification Δ pH and transient phenomena can be explained as result of H • and H′ translocation." @default.
- W2004683810 created "2016-06-24" @default.
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- W2004683810 date "1982-03-01" @default.
- W2004683810 modified "2023-09-26" @default.
- W2004683810 title "470—The proton pump at work" @default.
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- W2004683810 doi "https://doi.org/10.1016/0022-0728(82)85192-9" @default.
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