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- W2004686977 abstract "Abstract The transformation properties of the Born—Oppenheimer problem and of two probability densities for electronic singlet states of semirigid molecules are reviewed, based on the isometric group concept. A definition of sets of equivalent nuclei of semirigid molecules is put forward, which will be used to derive general transformation formulae for vector operators associated with nuclear spin operators of equivalent sets. Furthermore transformation formulae for general tensor operators and for phenomenological field gradient and spin—rotation coupling tensors of semirigid molecules will be presented and illustrated by examples. The phenomenological relations will be verified by considering the transformation properties of some of the relevant terms of the molecular hamiltonian." @default.
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- W2004686977 date "1985-01-01" @default.
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- W2004686977 title "Dynamics, hyperfine structure and symmetry of nonrigid molecules" @default.
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- W2004686977 doi "https://doi.org/10.1016/0022-2860(85)80104-6" @default.
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