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- W2004687239 abstract "Die früher an den gemischten Komplexsalzen des Typs K2[OsClnY6–n], Y = Br, J; n = 1–5 experimentell bestimmten kinetischen Daten für die intramolekulare Isomerisierung bzw. den intermolekularen Ligandenaustausch im festen Zustand werden auf die reinen Hexahalogenokomplexe extrapoliert. Bereits unter 100°C beginnt die Umlagerung innerhalb der einzelnen Oktaedergruppen, der intermolekulare Austausch der Liganden setzt erst bei deutlich höheren Temperaturen ein. Für die Reaktionsgeschwindigkeiten gelten folgende Reihen: intramolekular: K2[OsCl6] < K2[OsBr6] < K2[OsJ6], intermolekular: K2[OsJ6] < K2[OsCl6] < K2[OsBr6]. Ligand Exchange in Solid Complex Salts. III. Mobility of Ligands in Pure Hexahalo Complexes of Osmium(IV) The kinetical dates of intramolecular isomerization and intermolecular ligand exchange in solid-state, formerly determined experimentally for mixed-ligand complexes of the type K2[OsClnY6–n], X = Br, I; n = 1–5, are now extrapolated to pure hexahalo-complexes. Already below 100°C the rearrangement within the octahedral groups begins, the intermolecular ligand exchange just arises at distinct higher temperatures. For the rates the following series are valid: intramolecular: K2[OsCl6] < K2[OsBr6] < K2[OsI6], intermolecular: K2[OsI6] < K2[OsCl6] < K2[OsBr6]." @default.
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- W2004687239 date "1974-11-01" @default.
- W2004687239 modified "2023-09-23" @default.
- W2004687239 title "Platzwechselvorg�nge der Liganden in festen Komplexsalzen. III. Ligandenbeweglichkeit in reinen Hexahalogenokomplexsalzen von Osmium(IV)" @default.
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