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- W2004690666 abstract "Studies of the homogenous reaction kinetics of flame intermediates yield a reaction mechanism for the combustion of simple hydrocarbons. On the basis of such a mechanism the inhibition of flames by halogenated compounds and inorganic salts may be interpreted in terms of the removal of specific chain carriers as a result of: (1) their replacement by halogen atoms which no longer can lead to branching reactions, or (2) their homogeneous recombination catalyzed by alkali atoms. The interaction of free radicals with solid surfaces may result in chemical reaction with the substrate and the formation of a volatile or nonvolatile product, or the reaction with the adsorbate. Measurements of the surface-catalyzed recombination of atoms have demonstrated the controlling effect of energy transfer to the solid in such exothermic heterogeneous reactions involving hydrogen or oxygen atoms. In the case of Pyrex glass and quartz a change in the order of the surface reaction with temperature has been noted. A number of tables are presented which summarize the available information on the catalytic efficiencies of various solids for atom recombination." @default.
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- W2004690666 date "1963-01-01" @default.
- W2004690666 modified "2023-09-25" @default.
- W2004690666 title "Homogeneous and heterogeneous reactions of flame intermediates" @default.
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- W2004690666 doi "https://doi.org/10.1016/s0082-0784(63)80081-8" @default.
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